Robust and Transparent Lossless Directional Omniphobic Ultra-Thin Sticker-Type Film with Re-entrant Micro-Stripe Arrays

ACS Appl Mater Interfaces. 2022 Aug 31;14(34):39646-39653. doi: 10.1021/acsami.2c12398. Epub 2022 Aug 18.

Abstract

Directional droplet-sliding control without wetting the surface is immensely required in advanced surface engineering, including biological and chemical analyses or green technology. However, the development of robust and transparent thin sticker-type directional omniphobic films for portable usage in smart microfluidic platforms is rare. In this study, we report a novel perfluoropolyether (PFPE) directional omniphobic film (PDOF). The PDOF is a robust and transparent ultra-thin sticker-type film that can control the anisotropic sliding of various liquid droplets on the surface. The PFPE is a chemically stable and turgid material compared to polydimethylsiloxane (PDMS), which is often used to fabricate liquid-repellent thin films. A well-designed fabrication criterion through adhesion engineering in the soft-molding process was developed using the PFPE to obtain a PDOF with a thickness of 56 μm, with re-entrant micro-stripe structures on the surface. The fabricated PDOF showed intriguing liquid sliding properties based on the direction and spacing of the microstructures. This aspect is defined as an anisotropic factor.

Keywords: anisotropic sliding; directional omniphobic; perfluoropolyether; re-entrant micro-stripe; ultra-thin sticker-type film.