Photoactive carbon monoxide-releasing coordination polymer particles

Arnau Carné-Sánchez; Shuya Ikemura; Reiko Sakaguchi; Gavin A Craig; Shuhei Furukawa

doi:10.1039/d2cc03907a

Photoactive carbon monoxide-releasing coordination polymer particles

Chem Commun (Camb). 2022 Sep 1;58(71):9894-9897. doi: 10.1039/d2cc03907a.

Authors

Arnau Carné-Sánchez^{1

2}, Shuya Ikemura^{1

3}, Reiko Sakaguchi¹, Gavin A Craig^{1

4}, Shuhei Furukawa^{1

3}

Affiliations

¹ Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan. shuhei.furukawa@icems.kyoto-u.ac.jp.
² Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology Campus UAB, Bellaterra, 08193 Barcelona, Spain.
³ Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
⁴ Department of Pure and Applied Chemistry, University of Strathclyde, G1 1XL Glasgow, Scotland, UK.

PMID: 35975475
DOI: 10.1039/d2cc03907a

Abstract

We report the synthesis of photoactive carbon monoxide-releasing coordination polymer particles through the assembly of Mn(I) carbonyl complexes with bis(imidazole) ligands. The use of Mn(I) carbonyl complexes as metallic nodes in the coordination network avoids the potential for aggregation-induced self-quenching, favouring their use in the solid state.

MeSH terms

Carbon Monoxide*
Coordination Complexes*
Ligands
Polymers

Substances

Coordination Complexes
Ligands
Polymers
Carbon Monoxide