2-Amino-4-ferrocenyl-thia-zole

Bertin Anzaldo; Pankaj Sharma; Claudia P Villamizar; Rene Gutierrez Perez; Rubén A Toscano

doi:10.1107/S2056989022007228

2-Amino-4-ferrocenyl-thia-zole

Acta Crystallogr E Crystallogr Commun. 2022 Jul 19;78(Pt 8):818-820. doi: 10.1107/S2056989022007228. eCollection 2022 Aug 1.

Authors

Bertin Anzaldo¹, Pankaj Sharma¹, Claudia P Villamizar¹, Rene Gutierrez Perez², Rubén A Toscano¹

Affiliations

¹ Instituto de Química, Circuito Exterior Cd. Universitaria, PO Box 04510, Ciudad de México, Mexico.
² Lab. Síntesis de Complejos, Fac. Cs. Quím.-BUAP, Ciudad Universitaria, PO Box 156, Puebla, Mexico.

Abstract

The title compound, [Fe(C₅H₅)(C₈H₇N₂S)], was synthesized by the direct reaction of acetyl-ferrocene, thio-urea and resublimed iodine. The structure shows one mol-ecule in the asymmetric unit. The amino-thia-zole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the crystal, pairs of complex mol-ecules inter-act via inter-molecular N-H⋯N hydrogen bonds, forming a cyclic dimer which then inter-acts with other dimers through C-H⋯π inter-actions.

Keywords: aminothiazole; crystal structure; ferrocene; thiazole.

Grants and funding

We thank the DGAPA (project IN209020) for financial support.