Insight into the existent state of nitrogen-doped carbon dots in titanate nanotubes and their roles played toward simultaneous removal of coexisted Cu2+ and norfloxacin in water

Abstract

In this work, nitrogen-doped carbon dots (NCDs) were introduced in different existent sites of titanate nanotubes (TNTs) by a facile synthesis, and their effects on surface potential, photoelectrochemical properties and simultaneous removal of coexisted Cu²⁺ and norfloxacin (NOR) performance in water were systematically investigated. Constructed NCDs-TNTs composite displayed superior performance towards the adsorption (ion exchange/coordination) of Cu²⁺ and adsorption-oxidization of NOR over the two individuals, mainly benefiting from the collaboration of NCDs in different existent states. The existence of TiNH chemical linkage was identified between TNTs and NCDs-OT (NCDs on the outer surface of TNTs), which not only modulates the surface potential to favor the external diffusion of Cu²⁺ or NOR⁺ from aqueous solution to the negatively charged NCDs-TNTs, but also facilitates the intraparticle transfer of contaminants to the reactive sites. In addition, the up-conversion light property of NCDs-OT and the interstitial NCDs-IT (NCDs on the inner surface of TNTs) doping in TNTs interact together to enable NCDs-IT-TNTs to fully absorb and utilize all visible light. The photoexcited electrons were further trapped by NCDs-OT to promote the photogenerated carrier separation. Adsorbed Cu²⁺ could also improve the performance of NCDs-TNTs toward NOR oxidization, mainly owing to the self-synchronous doping of adsorbed Cu²⁺ broadening light absorption area and acting as mediators for delivering electrons. This work provides unique insights into the structural design of composite materials for such combined contamination remediation in water.

Keywords: Combined contamination; Existent state; Nitrogen-doped carbon dots; Titanate nanotubes.