Through etherification reaction, epoxy propyl dimethyl dodecyl ammonium chloride (EPDMDAC) was grafted onto the surface of a cellulose acetate (CA) membrane to prepare a stable nonleaching antibacterial antifouling membrane (QCA-X). The results showed that with the extension of grafting reaction time, the quaternary ammonium salt groups on the membrane surface increased and the hydrophilicity was enhanced. Compared with those of the CA membrane, the filtration capacity and antifouling performance of the QCA-X membrane are improved. When the grafting time is 4 h, the water permeability and flux recovery rate of the QCA-4 membrane are increased by 139 and 21.5%, respectively. The QCA-X membrane showed excellent antibacterial performance, and the sterilization rate against S. aureus and E. coli was more than 99.99%. After four repeated antibacterial cycles, the bactericidal rates against S. aureus and E. coli were maintained at about 99.69 ± 0.02 and 99.98 ± 0.02%, respectively, with good antibacterial persistence. Moreover, the QCA-X membrane can effectively inhibit bacterial adhesion. Mild and simple EPDMDAC grafting modifications improve the antibacterial, antifouling, and antibioadhesion properties of the CA membrane, showing its application potential in long-term water treatment, especially in biofouling water treatment.
Keywords: antibacterial; antifouling; cellulose acetate; graft modification; quaternary ammonium salt.