Effective immobilization of geogenic As and Pb in excavated marine sedimentary material by magnesia under wet-dry cycle, freeze-thaw cycle, and anaerobic exposure scenarios

Abstract

Massive amounts of marine sedimentary materials with geogenic heavy metal(loids) are excavated by the subsurface construction projects and then exposed to weathering conditions, which pose potential threats to the environment. In the present study, 2 % magnesia (MgO) was applied to immobilize geogenic arsenic (As) and lead (Pb) in excavated marine sedimentary material. To better evaluate the immobilization efficiency under different environmental scenarios, the untreated and amended solids were subjected to wet-dry cycles, freeze-thaw cycles, and anaerobic incubation until 49 days. The leaching behaviors of As and Pb were investigated and their size fractionations in the leachates were compared. The results indicate that most Pb exists in particulate and agglomerated colloidal fractions (0.1-5 μm) in the leaching suspensions, while most As is found in dissolved forms (<0.1 μm). It is therefore necessary to consider the element type and exposure scenarios during environmental risk evaluation, particularly using the batch test as a routine compliance testing procedure. In the control test without MgO addition, the wet-dry cycle resulted in the "self-induced" immobilization of As and Pb. The pH decreases to the neutral range and the formation of amorphous Fe-(oxyhydr)oxides following pyrite oxidation largely explained the decreased As and Pb leaching. In comparison, the freeze-thaw cycle and anaerobic incubation tended to enhance As and Pb leaching. Overall, MgO addition significantly reduced the leachability of As and Pb and displayed sustained immobilization performance under all studied scenarios. These findings could be largely attributed to solid particle aggregation induced by MgO addition, including the adsorption of As and Pb onto newly formed Fe-(oxyhydr)oxides and/or MgSi precipitates. This study offers a simple and effective strategy for the sustainable management of excavated marine sedimentary materials contaminated by geogenic As and Pb.

Keywords: Arsenic; Exposure scenarios; Leaching; Lead; Magnesia treatment; Naturally-contaminated solid.