Palladium Supported on Porous Organic Polymer as Heterogeneous and Recyclable Catalyst for Cross Coupling Reaction

Guanying Shi; Zhenhua Dong

doi:10.3390/molecules27154777

Palladium Supported on Porous Organic Polymer as Heterogeneous and Recyclable Catalyst for Cross Coupling Reaction

Molecules. 2022 Jul 26;27(15):4777. doi: 10.3390/molecules27154777.

Authors

Guanying Shi¹, Zhenhua Dong²

Affiliations

¹ Institute of Agricultural Products Processing, Henan Academy of Agricultural Sciences, Zhengzhou 450002, China.
² College of Chemistry and Chemical Engineering, Henan University of Technology, Lianhua Street 100, Zhengzhou 450001, China.

Abstract

Palladium immobilized on an amide and ether functionalized porous organic polymer (Pd@AEPOP) is reported to be an effective heterogeneous catalyst for the Heck cross-coupling reaction of aryl iodides with styrene for the synthesis of diphenylethene derivatives. Excellent yields can be obtained using a 0.8 mol% Pd catalyst loading under the optimized reaction condition. The heterogeneous Pd@AEPOP catalyst can also be applied on the Suzuki reaction and the reduction of nitroarene.

Keywords: Heck reaction; heterogeneous catalysis; nanoparticles; palladium; porous organic polymer.

MeSH terms

Catalysis
Iodides
Palladium*
Polymers*
Porosity

Substances

Iodides
Polymers
Palladium

Grants and funding

This research received no external funding.