Normally-off Hydrogen-Terminated Diamond Field-Effect Transistor with SnOx Dielectric Layer Formed by Thermal Oxidation of Sn

Materials (Basel). 2022 Jul 21;15(14):5082. doi: 10.3390/ma15145082.

Abstract

SnOx films were deposited on a hydrogen-terminated diamond by thermal oxidation of Sn. The X-ray photoelectron spectroscopy result implies partial oxidation of Sn film on the diamond surface. The leakage current and capacitance-voltage properties of Al/SnOx/H-diamond metal-oxide-semiconductor diodes were investigated. The maximum leakage current density value at -8.0 V is 1.6 × 10-4 A/cm2, and the maximum capacitance value is measured to be 0.207 μF/cm2. According to the C-V results, trapped charge density and fixed charge density are determined to be 2.39 × 1012 and 4.5 × 1011 cm-2, respectively. Finally, an enhancement-mode H-diamond field effect transistor was obtained with a VTH of -0.5 V. Its IDMAX is -21.9 mA/mm when VGS is -5, VDS is -10 V. The effective mobility and transconductance are 92.5 cm2V-1 s-1 and 5.6 mS/mm, respectively. We suspect that the normally-off characteristic is caused by unoxidized Sn, whose outermost electron could deplete the hole in the channel.

Keywords: FET; SnOX; diamond; normally-off; thermal oxidation.