Boosting Hydrogen Evolution Reaction Activity of Amorphous Molybdenum Sulfide Under High Currents Via Preferential Electron Filling Induced by Tungsten Doping

Abstract

The lack of highly efficient, durable, and cost-effective electrocatalysts for the hydrogen evolution reaction (HER) working at high current densities poses a significant challenge for the large-scale implementation of hydrogen production from renewable energy. Herein, amorphous molybdenum tungsten sulfide/nitrogen-doped reduced graphene oxide nanocomposites (a-MoWS_x /N-RGO) are synthesized by plasma treatment for use as high-performance HER catalysts. By adjusting the plasma treatment duration and chemical composition, an optimal a-MoWS_x /N-RGO catalyst is obtained, which exhibits a low overpotential of 348 mV at a current density of 1000 mA cm^-2 and almost no decay after 24 h of working at this current density, outperforming commercial platinum/carbon (Pt/C) and previously reported heteroatom-doped MoS₂ -based catalysts. Based on density functional theory (DFT) calculations, it is found that with a reasonable tungsten doping level, the catalytic active site (2S^{2 -} ) shows excellent catalytic performance working at high current densities because extra electrons preferentially fill at 2S^{2 -} . The introduction of tungsten tends to lower the electronic structure energy, resulting in a closer-to-zero positive $\Delta G_{H^{\ast }}$ . Excessive tungsten introduction, however, can lead to structural damage and a worse HER performance under high current densities. The work provides a route towards rationally designing high-performance catalysts for the HER at industrial-level currents using earth-abundant elements.

Keywords: amorphous molybdenum tungsten sulfide; amorphous transition-metal sulfides; density functional theory; high current density; hydrogen evolution reaction; plasma treatment.