Molecular structure-tuned stability and switchability of CO2-responsive oil-in-water emulsions

Abstract

Hypothesis: Pseudo-Gemini surfactants (PGS) possessing switchable and recyclable features have drawn increasing attention on generating high-performance CO₂-responsive emulsions for wide range and versatile applications. However, there is a lack of fundamental understanding on how the molecular structure of PGS affects the stability and switchability of emulsions. We hypothesize that the length and type of the spacer in PGS play a decisive role in controlling interfacial and switching properties.

Experiments: Two series of PGS with different spacers were prepared through electrostatic association between amines and oleic acid. The interfacial activity and CO₂-responsive properties of corresponding emulsions were systematically investigated by well-designed experiments and molecular dynamics simulations.

Findings: Increasing the spacer length to allow the bent configuration leads to more tight arrangement of oleic molecules, consequently improving the interfacial activity. In addition, the introduction of amino group into the spacer dramatically promotes CO₂ response of resulting PGS due to ehanced migration of the spacer from the interface to the aqueous phase after CO₂ addition. These results are inspiring in designing controllable CO₂-responsive emulsions for a wide range of industrial applications (e.g., enhanced oil recovery and oil-contaminated soil remediation).

Keywords: CO(2)-responsive emulsion; Molecular dynamics simulation; Pseudo-Gemini surfactant; Spacer length and structure.