Electrochemical sensing of copper (II) ion in water using bi-metal oxide framework modified glassy carbon electrode

Abstract

In this research, an electrochemical sensor was fabricated employing the metal-organic framework (MOF) deposited glassy carbon electrode (GCE) for the sensing copper ions in water with high sensitivity. The porous nanostructured MOF was characterized through Transmission electron microscope, scanning electron microscope and X-ray diffraction analysis. The Bi-MOF nanostructure deposited GCE (Bi-MOF/GCE) was fabricated by drop-casting a suspension of Bi-MOF in water on GCE surface. The performance of modified electrode in the presence and absence of heavy metal ions such as Cd²⁺, Hg²⁺ As³⁺, Pb²⁺ and Cu²⁺ was determined by the cyclic voltammetry in deionised water within the scan rate range of 25 and 300 mVs^-1. The Bi-MOF/GCE displayed highest anodic and cathodic peak current for Cu²⁺ ions than other metal ions, which was enhanced linearly within the scan rate range of 10-100 mV s^-1. Under the employed experimental conditions, the fabricated Bi-MOF/GCE based electrochemical sensor showed an outstanding routine in the determination of copper with a lowest sensing limit of 1 × 10^-5 M, wide linear range variation, strong interaction between metal ions and Bi-MOF. It has long-term stability and good reproducibility. The Bi-MOF/GCE electrode was successfully tested to detect Cu²⁺ in tap water with acceptable results.

Keywords: Bi-MOF; Copper sensor; Electrochemical metal sensor; Heavy metal sensor; Metal oxide frameworks; Modified GCE.