Chemobrionics is a research field about the well-known self-organized inorganic structures. Numerous research works have focused on controlling their growth pattern and characteristic features. In the present study, a controlled injection method is proposed to produce more regular self-assembled chemobrionics compared to the standard direct injection technique. This method involves the injection of a metal salt solution into an agarose support template filled with an anionic solution. The obtained structures were studied by scanning electron microscopy, X-ray microtomography, X-ray photoelectron spectroscopy, Raman spectroscopy, Fourier-transform IR spectroscopy, and thermogravimetric analysis. Despite the complex mechanism and chemistry underlying the self-organization phenomena, the controlled injection method enabled the generation of regular standard chemobrionic structures with high experimental reproducibility. It provided the extraction of tubular structures from the reaction vessel without breakage, thus allowing comprehensive characterization. Furthermore, the morphological, chemical, and thermal features of these structures were highly correlated with the standard chemobrionics obtained in the direct injection method. The proposed controlled injection method holds great promise for understanding and controlling the properties of chemobrionics and related structures.
© 2022 The Authors. Published by American Chemical Society.