Effects of Fly Ash Inclusion and Alkali Activation on Physical, Mechanical, and Chemical Properties of Clay

Materials (Basel). 2022 Jul 1;15(13):4628. doi: 10.3390/ma15134628.

Abstract

This study investigated the improvement in the behaviour of a clay soil due to the addition of alkali-activated fly ash as a stabilising agent, and the effects of different activation factors such as alkali dosages and silica moduli. The alkali activator solution used was a mixture of sodium silicate and sodium hydroxide. Class F fly ash was used as the precursor material for the geopolymerisation process. Soil samples stabilised with non-activated class F fly ash were prepared and tested to compare the results with samples stabilised with alkali-activated fly ash. Compaction tests, unconfined compressive strength tests, X-ray diffraction analysis, and scanning electron microscopy analysis were carried out on samples cured 1, 7, and 28 days at room conditions. The results showed that the compressive strength of stabilised soil significantly increased when the fly ash was activated. The optimal activation parameters to stabilise the soil were found to be alkali dosages in the range of 12% to 16% and a silica modulus of 1.25. The highest compressive strength recorded was at 1293 kPa with an alkali dosage of 16% and a silica modulus of 1.25, while for the non-stabilised soil, it was at 204 kPa at 28 days of curing. Mineralogical analysis showed a decrease in the peak intensities of kaolinite and illite, while microstructural analysis indicated an alteration in soil texture with the addition of the alkali-activated fly ash.

Keywords: SEM; XRD; alkali compounds; compaction; compressive strength; fly ash; soil stabilisation.