Design and synthesis of cellulose nanofiber-derived CoO/Co/C two-dimensional nanosheet toward enhanced and stable lithium storage

Abstract

Nano-sized two-dimensional carbonaceous materials have been widely used as the matrix for alloying-type and conversion-type anode materials for Li-ion batteries (LIBs) to improve structural stability and rate performance. However, relevant synthesis usually requires rigorous conditions and chronic reaction processes. Herein, we have designed a simple solvothermal reaction and heat treatment to prepare a novel CoO/Co/C two-dimensional nanosheet (CoO/Co/C 2DNS) by adopting cellulose nanofibers (CNFs) as the precursor. The unique characteristics of CNFs facilitate the uniform distribution of active materials on the surface and the construction of two-dimensional nanostructure via self-assembly. It is worth noting that CoO/Co/C 2DNS exhibits a striking synergistic effect since the porous 2D carbon framework offers additional pseudo-capacitance and enhances the electronic conductivity, while the ultrafine active materials encapsulated inside shorten the Li-ions diffusion pathways and relieve the volume change. Benefit from the unique structure, the composite anode delivered outstanding rate performance (∼500 mAh g^-1 at 10 A g^-1) and superior long-range cycling performance up to 800 cycles even at 2 A g^-1. This work provides a new strategy for the synthesis of nano-sized 2D composite, offering a promising route to construct high performance conversion-type anodes for next-generation LIBs.

Keywords: Cellulose nanofibers; CoO/Co/C two-dimensional nanosheet; Conversion-type anode materials; Lithium-ion batteries; Pseudo-capacitance.