Treatment of Saussurea heteromalla for biofuel synthesis using catalytic membrane reactor

Abstract

Membrane technology has been adopted as a prospective and promising alternative to the standard technology used for biodiesel production since the time when it had some limitations. During this research project, the inedible seed oil generating feedstock known as Saussurea heteromalla was put through a biodiesel production process that utilized membrane technology with an effort to increase the yield of methyl ester. The transesterification process was mediated by zirconium oxide nanoparticles that were generated using an aqueous extract of Portulaca oleracea leaf. With an oil to methanol ratio of 1:9, a catalyst concentration of 0.88 (wt. %), temperature of 87 °C, and reaction time of 180 min, the highest possible biodiesel yield of 93% was achieved. The findings of the catalyst characterization demonstrated the purity of the zirconium oxide nano particles and their nanoscale nature with average particle size of 31 nm. Using gas chromatography and mass spectrometry (GC/MS), an examination of biodiesel revealed the presence of four different peaks of methyl esters. Using Fourier-transform infrared spectroscopy (FTIR) and nuclear magnetic resonance, we were able to verify that the production of methyl esters in the biodiesel sample was successful (NMR). Zerconium oxide nanoparticles were found reusable up to five consecutive cycles of transesterification. The fuel-related properties of methyl ester have been determined and are in line with the requirements of the international standards ASTM D-6571 and EN 14214. In the course of our ongoing research, we made use of membrane technology, which led to the production of biodiesel from the seed oil of Saussurea heteromalla that was better for the environment, more cost effective, and produced in greater quantities.

Keywords: Biodiesel; Green nanoparticles; Membrane technology; Saussurea heteromalla; Treatment; Zirconium oxide catalyst.