Seasonal variation and source apportionment of inorganic and organic components in PM2.5: influence of organic markers application on PMF source apportionment

Abstract

PM_2.5 samples collected over a 1-year period in a Chinese megacity were analyzed for organic carbon (OC), elemental carbon (EC), water-soluble ions, elements, and organic markers such as polycyclic aromatic hydrocarbons (PAHs), hopanes, steranes, and n-alkanes. To study the applicability of organic markers in source apportionment, the relationship between organic and inorganic components was analyzed, and four scenarios were implemented by incorporating different combinations of organic and inorganic tracers. The consistent temporal variations trend of 4-ring PAHs and SO₄^2- prove that coal burning directly emits a portion of sulfate. The concentrations of ∑5-7-ring PAHs, NO₃^-, and NO₂ show a trend of simultaneous increase and decrease, implying collective impacts from the vehicle source. The concentrations of OC and EC positively correlate with the 5-7-ring PAHs and Cu and Zn, which proves that part of Cu and Zn comes from vehicle emissions. Five factors were identified by incorporating only conventional components, including secondary source (SS, 30%), fugitive dust (FD, 14%), construction dust (CD, 4%), traffic source (TS, 19%), and coal combustion (CC, 14%). Six factors were identified by incorporating conventional components and PAHs, including SS (28%), FD (15%), CD (4%), CC (13%), gasoline vehicles (GV, 12%), and diesel vehicles (DV, 10%). Eight factors were identified by incorporating conventional components, PAHs, hopanes, and n-alkanes, including SS (26%), FD (17%), CD (3%), GV (14%), DV (8%), immature coal combustion (ICC, 5%), mature coal combustion (MCC, 10%), and biogenic source (BS, 1%).

Keywords: Organic markers; PM2.5; PMF; Source apportionment.