Influencing Factors of Surfactant Stripping Crude Oil and Spontaneous Imbibition Mechanism of Surfactants in a Tight Reservoir

ACS Omega. 2022 May 26;7(22):19010-19020. doi: 10.1021/acsomega.2c02190. eCollection 2022 Jun 7.

Abstract

Surfactants play a vital role in the working fluid during the exploitation of tight reservoirs. The main goal is to clarify the mechanism of surfactant production enhancement in the reservoir. In this paper, starting from the interface properties and emulsifying properties of surfactants, the factors affecting the stripping of crude oil by different surfactants were described in detail. Meanwhile, the imbibition experiments of cores were used to clarify the two spontaneous imbibition mechanisms of the surfactant. Namely, they are the capillary force expulsion caused by the emulsion stripping thermal diffusion-convection and the wettability change. When the interfacial tension between the surfactant and oil is in the range of 10-2-10-3 mN/m, the particle size of emulsion is less than 1 μm, and the oil stripping efficiency is greater than 58%. The imbibition is mainly caused by thermal diffusion-convection. The wetting angle of the surfactant mainly changing wettability is less than 15°, and the adhesion work is greater than 52 mN/m. Using X-ray computed tomography, the surfactant imbibition distance of different permeability types of cores was obtained. The results show that higher permeability cores have a deeper imbibition distance. The results of this paper enrich the mechanism of enhanced oil recovery by surfactants and have important implications for the exploitation of tight reservoirs.