Cooperative catalysis in a metal-organic framework via post-synthetic immobilisation

Yohei Takashima; Yuya Suwaki; Takaaki Tsuruoka; Kensuke Akamatsu

doi:10.1039/d2dt01544g

Cooperative catalysis in a metal-organic framework via post-synthetic immobilisation

Dalton Trans. 2022 Jun 21;51(24):9229-9232. doi: 10.1039/d2dt01544g.

Authors

Yohei Takashima¹, Yuya Suwaki¹, Takaaki Tsuruoka¹, Kensuke Akamatsu¹

Affiliation

¹ Department of Nanobiochemistry, Frontiers of Innovative Research in Science and Technology (FIRST), Konan University, 7-1-20 Minatojimaminamimachi, Chuo-ku, Kobe 650-0047, Japan. takashim@konan-u.ac.jp.

PMID: 35670585
DOI: 10.1039/d2dt01544g

Abstract

Herein, we generated a series of cooperative catalysts via post-synthetic immobilisation of a Co(salen) complex in a metal-organic framework (MOF). By tuning the amount of Co(salen) in the MOF, the cooperative catalytic activities can be successfully optimised.