Electrocoagulation (EC) in water treatment encounters several challenges, such as electrode fouling and passivation, especially when the effluent has a complex composition, such as produced water in the oil and gas industry. In this study, the effectiveness of applying an external magnetic field during EC with aluminum anodes (Al-EC) or mild steel anodes (Fe-EC) was investigated for the first time for the removal of inorganic contaminants (including silica, calcium, magnesium, and sulfide) from synthetic and field samples of produced waters. For Al-EC, the presence of a magnetic field perpendicular to the electric field was found to enhance the treatment performance and mitigate the fouling formation on the electrode surface. Chronoamperometric investigations indicated that the application of MF in Al-EC enhances the current density and reduces the time to form a fouling layer on the electrode. In contrast, with Fe-EC, the presence of the magnetic field increased the rate of fouling on the electrodes. Potentiodynamic and kinetic investigations indicate that the magnetic field improves mass transfer via Kelvin force and magnetohydrodynamic (MHD) effects with no impact on the type of kinetic model, while the change in the spin states of the accumulated species has a negligible impact on reducing the fouling. The resistivity of the accumulated fouling layer (δRF) was found to reduce by around 23% due to a magnetic field of 0.158 T. Although increasing the strength of the applied MF increases the mass transfer, the effect is not linear. The results indicate that applying a magnetic field in Al-EC can be an effective method to mitigate fouling during water treatment.
Keywords: Aluminum electrode; Electrocoagulation; Kelvin force; Magnetic field; Magnetohydrodynamics; Spin states.
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