NaOH-assisted H2O2 post-modification as a novel approach to enhance adsorption capacity of residual coffee waste biochars toward radioactive strontium: Experimental and theoretical studies

Abstract

In this study, NaOH-assisted H₂O₂ post-modification was proposed as a novel strategy to enhance the adsorption of radioactive strontium (Sr) onto residual coffee waste biochars (RCWBs). To validate its viability, the adsorption capacities and mechanisms of Sr(II) using pristine (RCWB_P), H₂O₂ post-modified (RCWB_HP), and NaOH-assisted H₂O₂ post-modified residual coffee waste biochars (RCWB_NHP) were experimentally and theoretically investigated. The highest adsorption capacity of Sr(II) for RCWB_NHP (10.91 mg/g) compared to RCWB_HP (5.57 mg/g) and RCWB_P (5.07 mg/g) was primarily attributed to higher negative surface zeta potential (RCWB_NHP = -5.66 → -30.97 mV; RCWB_HP = -0.31 → -11.29 mV; RCWB_P = 1.90 → -10.40 mV) and decoration of Na on the surfaces of RCWB_P via NaOH-assisted H₂O₂ post-modification. These findings agree entirely with the theoretical observations that the adsorption of Sr(II) onto RCWB_P and RCWB_HP was controlled by electrostatic interactions involving carbonyls whereas enriched carboxylic acids and decorated Na on the surfaces of RCWB_NHP through the replacement of Mg and K by NaOH-assisted H₂O₂ modification stimulated electrostatic interactions and cation exchanges governing the adsorption of Sr(II). Hence, NaOH-assisted H₂O₂ post-modification seemed to be practically applicable for improving the adsorption capacity of Sr(II) using RCWB-based carbonaceous adsorbents in real water matrices.

Keywords: Cation-exchange capacity; Density functional theory calculations; NaOH-assisted H(2)O(2) treatment; Radioactive strontium; Residual coffee waste biochars.