Characterization and biodegradation of ternary blends of lignosulfonate/synthetic zeolite/polyvinylpyrrolidone for agricultural chemistry

Abstract

This study investigates novel ternary polymer blends based on polyvinylpyrrolidone (PVP) as the matrix in combination with lignosulfonate and synthetic zeolite. The blends were prepared by the casting method, and their properties were analysed by various techniques, i.e. FTIR analysis, differential scanning calorimetry and thermogravimetric analysis, including tests for water solubility and uptake, and determination of adhesion and hardness. The biodegradation of the blends in soil was also evaluated, and an experiment was conducted on plant growth (Sinapis alba). Optical microscopy showed that particles of the synthetic zeolite were relatively evenly distributed in the polymer matrix, forming random networks therein. The FTIR spectra for the blends proved that hydrogen bonding interactions had occurred between the PVP/synthetic zeolite and PVP/lignosulfonate. DSC analysis confirmed the good miscibility of the PVP and lignosulfonate. TGA results indicated that the thermal stability of the PVP was maintained. Lignosulfonate had the effect of reducing the adhesion of the blends. However, it was revealed that effect depends greatly on the presence of zeolite and the concentration of lignosulfonate. The obtained results showed that the optimal composition of the blend is 2.5 wt% of zeolite and 5 wt% of lignosulfonate into the PVP. Its water solubility and uptake was satisfactory from the perspective of handling and further utilization. A respirometric biodegradation test confirmed that the ternary blend was environmentally friendly, in addition to which a germination experiment evidenced that the lignosulfonate and synthetic zeolite promoted the root growth and development of S. alba. From these findings it was concluded that the novel ternary polymer blend was applicable as either as seed carriers (in the form of seed tapes) or as a biocompatible coating to protect seeds.

Keywords: Adhesion; Lignosulfonate; Polyvinylpyrrolidone; Sinapis alba; Soil microorganisms; Synthetic zeolite.