An [FeIII8] molecular oxyhydroxide

Daniel J Cutler; Marco Coletta; Mukesh K Singh; Angelos B Canaj; Laura J McCormick; Simon J Coles; Jürgen Schnack; Euan K Brechin

doi:10.1039/d2dt01477g

An [Fe^III₈] molecular oxyhydroxide

Dalton Trans. 2022 Jun 13;51(23):8945-8948. doi: 10.1039/d2dt01477g.

Authors

Daniel J Cutler¹, Marco Coletta¹, Mukesh K Singh¹, Angelos B Canaj¹, Laura J McCormick², Simon J Coles², Jürgen Schnack³, Euan K Brechin¹

Affiliations

¹ EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, EH9 3FJ, Scotland, UK. E.Brechin@ed.ac.uk.
² EPSRC National Crystallography Service, School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UK.
³ Universitat Bielefeld, Postfach 100131, D-33501 Bielefeld, Germany. jschnack@uni-bielefeld.de.

PMID: 35611692
DOI: 10.1039/d2dt01477g

Abstract

An [Fe^III₈] hexagonal bipyramid displays antiferromagnetic exchange between the two capping tetrahedral ions and the six ring octahedral ions resulting in a spin ground state of S = 10.