The simultaneous removal of co-contaminants pyrene and Cu (II) from aqueous solutions by Fe/Mn bimetallic functionalized mesoporous silica

Abstract

In recent years, the co-contamination of heavy metals (HMs) and polycyclic aromatic hydrocarbons (PAHs) has attracted more and more attention, and finding efficient and coordinated removal method has been the hot focus. In this study, Fe/Mn-SBA15 bimetallic mesoporous silica adsorbent (Fe/Mn-SBA15) was prepared by hydrothermal method with the functional groups Fe and Mn simultaneously doped into the framework structure of SBA15. Fe/Mn-SBA15 was systematically characterized by XRD, TEM, and BET and used in removal of typical PAHs-pyrene and heavy metal-Cu (II) from aqueous solutions simultaneously. The single and binary adsorption behaviors were studied by kinetics, isotherm, pH, and ionic strength. The results showed that the functional groups of Fe and Mn were successfully loaded into the structure of SBA15 and the prepared adsorbent was still a typical mesoporous adsorbent. The adsorption of pyrene and Cu (II) onto Fe/Mn-SBA15 was fast and the adsorption equilibrium was achieved in 100 min. The Langmuir model fitted the adsorption isotherm better and the maximum adsorption capacities for pyrene and Cu (II) were 120 mg/g and 10.52 mg/g, respectively. The increase of ionic strength could enhance and decrease the adsorption capacity of pyrene and Cu (II), which may be attributed to salting-out effect and potassium competitive. With the increase of pH values, the negative charge on the surface of the adsorbent increased, resulting in the decrease and increase of adsorption capacity of pyrene and Cu (II) onto Fe/Mn-SBA15. In addition, Fe/Mn-SBA15 was found to have a synergistic effect on the adsorption of pyrene and Cu (II). This result is mainly due to the formation of hydration complex by pyrene-Cu (II) through cation-π interaction, which increases the adsorption capacity by occupying each other's adsorption sites of adsorbent. This study provides a new method for the synergistic removal of PAHs and HMs from aqueous solutions.

Keywords: Adsorption; Cu (II); Fe/Mn bimetallic; Functionalized mesoporous silica; Pyrene; SBA15.