Recent advances in the tuning of the organic framework materials - The selections of ligands, reaction conditions, and post-synthesis approaches

Abstract

Organic framework materials, particularly metal-organic frameworks (MOFs), graphene-organic frameworks (GOFs), and covalent organic frameworks (COFs), have led to the revolution across fields including catalysts, sensors, gas capture, and biology mainly owing to their ultra-high surface area-to-volume ratio, on-demand tunable crystal structures, and unique surface properties. While the wet chemistry routes have been the predominant synthesis approach, the crystal phase, morphological parameters, and physicochemical properties of organic framework materials are largely affected by various synthesis parameters and precursors. In this work, we specifically review the influences of synthesis parameters towards crystal structures and chemical compositions of organic framework materials, including selected ligand types and lengths, reaction temperature/solvent/reactant compositions, as well as post-synthesis modification approaches. More importantly, the subsequent impacts on the general electronic, mechanical, surface chemical, and thermal properties as well as the consequent variation in performances towards catalytic, desalination, gas sensing, and gas storage applications are critically discussed. Finally, the current challenges and prospects of organic framework materials are provided.

Keywords: Length of ligand; Ligand; Organic framework; Properties; Structural design; Tuning.