Tb3+/Sm3+ co-doped double perovskite: synthesis, exfoliation and luminescence properties

Mingjun Bai; Ying Zhang; Hao Wan; Gen Chen; Xiaohe Liu; Renzhi Ma

doi:10.1039/d2cc02091b

Tb³⁺/Sm³⁺ co-doped double perovskite: synthesis, exfoliation and luminescence properties

Chem Commun (Camb). 2022 Jun 8;58(46):6626-6629. doi: 10.1039/d2cc02091b.

Authors

Mingjun Bai¹, Ying Zhang², Hao Wan², Gen Chen¹, Xiaohe Liu^{1

2}, Renzhi Ma³

Affiliations

¹ School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083, P. R. China. liuxh@csu.edu.cn.
² School of Chemical Engineering, Zhengzhou University, Zhengzhou 45001, P. R. China. wanhao@zzu.edu.cn.
³ International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan.

PMID: 35587683
DOI: 10.1039/d2cc02091b

Abstract

Tb³⁺/Sm³⁺ co-doped double perovskite K[K_1.5(Tb_1-xSm_x)_0.5]Ta₃O₁₀ (denoted as KKT_1-xS_xTO) was prepared, which exhibited typical Tb³⁺ and Sm³⁺ photoluminescence emissions and tunable colours. After protonation and subsequent exfoliation processes, unilaminar KT_1-xS_xTO nanosheets with a lateral size of ∼300 nm and thickness of ∼2.7 nm were obtained.