Antifouling Mortars for Underwater Restoration

Nanomaterials (Basel). 2022 Apr 28;12(9):1498. doi: 10.3390/nano12091498.

Abstract

This research has focused on the assessment of the compositional features and mechanical and antifouling performances of two different mortars formulated for an underwater setting, and which contain Mg(OH)2 as an antifouling agent. Regarding the mechanical characterization, the uniaxial compressive strength and flexural strength were measured. The composition of the materials was explored by differential thermal/thermogravimetric analysis (DTA-TG), X-ray diffraction analysis (XRPD), and scanning electronic microscopy (SEM) coupled with EDS microanalysis. The assessment of the biological colonization was evaluated with colorimetric analysis and image analysis. The results suggest that both mortars have good mechanical resistance once set underwater. Moreover, the adding of Mg(OH)2 improves the resistance toward biofouling; this was observed both in laboratory and sea-exposed specimens.

Keywords: biofouling; geomaterials; magnesium hydroxide; mortars; nanoparticles; restoration; submerged sites.

Grants and funding

This research was conducted within the frame of the MaTaCoS project (Advanced materials and technologies applied to the conservation of underwater cultural heritage) funded by MISE (Italian Ministry of Economic Development), PON “Ricerca e Innovazione” 2014–2020—Fondo sociale europeo, Azione 1.2 “Mobilità dei Ricercatori” (AIM “Attraction and International Mobility”—LINEA 1. Both projects concern the design of advanced tools and methods for the protection of Underwater Cultural Heritage, through specific cleaning and consolidating procedures to be applied directly in situ) and TOP Heritage project (P2018/NMT-4372) of the Community of Madrid.