Hierarchical nanostructured electrodes with excellent electronic properties and high specific surface areas have promising applications in high-performance supercapacitors. However, high active mass loading and uniform structure are still crucial in fabricating such architectures. Herein, Co(OH)2 nanoflakes were homogeneously deposited on nickel nanowire arrays (NNA) through a hydrothermal approach to form an NNA@Co(OH)2 (NNACOH) composite electrode. The as-synthesized one dimensional (1D) system had a lavender-like structure with a high mass loading of 5.42 mg cm-2 and a high specific surface area of 74.5 m2 g-1. Due to the unique electrode structure characteristics, the electrode could deliver a high specific capacitance of 891.2 F g-1 at the current density of 1 A g-1 (corresponding to an areal capacitance of 4.83 F cm-2 at 5.42 mA cm-2). The capacitance could still maintain a high value of 721 F g-1 when the current density is increased to 50 A g-1. In addition, the electrode showed superior cycle stability with a capacitance retention of 89.3% after charging/discharging at the current density of 10 A g-1 for 20 000 cycles. A flexible asymmetric supercapacitor (ASC) was assembled by employing NNACOH as the positive electrode and activated carbon (AC) as the negative electrode. It delivered a maximum energy density of 23.1 W h kg-1 at the power density of 712 W kg-1 and an energy density of 13.5 W h kg-1 at the maximum power density of 14.7 kW kg-1 (based on the total mass of the electrodes), showing the state-of-the-art energy storage ability of the Co(OH)2 cathode material at device level.
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