A high-efficient and recyclable aged nanoscale zero-valent iron compound for V5+ removal from wastewater: Characterization, performance and mechanism

Abstract

An effective complex of nanoscale zero-valent iron (NZVI) supported on zirconium 1,4-dicarboxybenzene metals-organic frameworks (UIO-66) with strong oxidation resistance was synthesized (NZVI@UIO-66) for V⁵⁺ removal from wastewater. The results demonstrated that NZVI was successfully loaded on UIO-66 with a uniform dispersion, and then the composite was aged in the air which was named A-NZVI@UIO-66. V⁵⁺ could be removed quickly and completely using A-NZVI@UIO-66 in a wider pH range except for the pH = 1 condition. The reaction between A-NZVI@UIO-66 and V⁵⁺ was an endothermic process. Freundlich model with a better-fitted value showed the adsorption of V⁵⁺ on A-NZVI@UIO-66 was multi-layer heterogeneous adsorption and the adsorbed amount of V⁵⁺ was 397.23 mg V/g NZVI. Nitrate had a competitive inhibition on V⁵⁺ removal by A-NZVI@UIO-66. Mechanisms of vanadium elimination from the aqueous phase by A-NZVI@UIO-66 included physical adsorption, reduction, and complex co-precipitation, particularly the reduction dominated. The subsistent Zr-O bond in A-NZVI@UIO-66 provided a possible double reaction path by playing an electron donor, storage, or conductor role. After acid leaching, A-NZVI@UIO-66 represented good reusability in the removal of V⁵⁺ from the practical mine sewage.

Keywords: Mechanism; Nanoscale zero-valent iron; Recyclability; UIO-66 (Zr–O); Vanadium.