Graphene is considered to be a potential replacement for the traditional Pt counter electrode (CE) in dye-sensitized solar cells (DSSCs). Besides a high electron transport ability, a close contact between the CE and electrolyte is crucial to its outstanding catalytic activity for the I3 -/I redox reaction. In this study, reduced graphene oxide (RGO) and three-dimensional graphene networks (3DGNs) were used to fabricate the CE, and the graphene-based CE endowed the resulting DSSC with excellent photovoltaic performance features. The high quality and continuous structure of the 3DGNs provided a channel amenable to fast transport of electrons, while the RGO afforded a close contact at the interface between the graphene basal plane and electrolyte. The obtained energy conversion efficiency (η) was closely related to the mass fraction and reduction degree of the RGO that was used. Corresponding optimization yielded, for the DSSCs based on the 3DGN-RGO CE, a value of η as high as 9.79%, comparable to that of the device using a Pt CE and hence implying promising prospects for the as-prepared CE.
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