Facile sub-/supercritical water synthesis of nanoflake MoVTeNbO x -mixed metal oxides without post-heat treatment and their catalytic performance

Abstract

A fast and simple sub-/supercritical water synthesis method is presented in this work in which MoVTeNbO _x -mixed metal oxides with various phase compositions and morphologies could be synthesized without post-heat treatment. It was demonstrated that the system temperature for synthesis had a significant influence on the physico-chemical properties of MoVTeNbO _x . Higher temperatures were beneficial for the formation of a mixed crystalline phase containing TeVO₄, Te₃Mo₂V₂O₁₇, Mo₄O₁₁ and TeO₂, which are very different from the crystalline phases of conventional Mo-V-Te-Nb-mixed metal oxides. While at lower temperatures, Mo₄O₁₁ was replaced by Te. At high temperature, the as-prepared samples presented distinct nanoflake morphologies with an average size of 10-60 nm in width and exhibited excellent catalytic performances in the selective oxidation of propylene to acrylic acid. It is illustrated that the large specific surface area, presence of Mo₄O₁₁ and superficial Mo⁶⁺ and Te⁴⁺ ions are responsible for the high propylene conversion, while suitable acidic sites and superficial Nb⁵⁺ ions improved the selectivity to acrylic acid.