Phosphorus/nitrogen co-doped and bimetallic MOF-derived cathode for all-solid-state rechargeable zinc-air batteries

Xing Yang; Xianghua Wu; Zeping Guo; Qingyu Li; Hongqiang Wang; Chujun Ke; Wei Zeng; Xiafei Qiu; Yun He; Xiaoguang Liang; Yoonseob Kim

doi:10.1039/d0ra04827e

Phosphorus/nitrogen co-doped and bimetallic MOF-derived cathode for all-solid-state rechargeable zinc-air batteries

RSC Adv. 2020 Sep 10;10(55):33327-33333. doi: 10.1039/d0ra04827e. eCollection 2020 Sep 7.

Authors

Xing Yang¹, Xianghua Wu¹, Zeping Guo¹, Qingyu Li^{2

3}, Hongqiang Wang^{2

3}, Chujun Ke¹, Wei Zeng¹, Xiafei Qiu¹, Yun He^{1

3}, Xiaoguang Liang^{1

2

4}, Yoonseob Kim⁵

Affiliations

¹ Department of Physics, Guangxi Normal University Guilin China.
² Guangxi Key Laboratory of Low Carbon Energy Materials, Guangxi Normal University Guilin China.
³ State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University Guilin China.
⁴ Guangxi Key Laboratory of Nuclear Physics and Technology, Guangxi Normal University Guilin China.
⁵ Department of Chemical and Biological Engineering, Hong Kong University of Science and Technology Clear Water Bay Kowloon Hong Kong SAR China.

Abstract

With the merits of high safety and energy density, all-solid-state zinc-air batteries possess potential applications in flexible and wearable electronic devices. Especially, the air cathodes with bifunctional catalytic activity, i.e. oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) have been received enormous attention. In this work, we provide a novel phosphorus/nitrogen co-doped and bimetallic metal-organic framework (MOF)-derived cathode configurated with phosphorus-doped bimetallic FeNi alloys and a nitrogen-doped porous carbon layer loaded on graphene (P-FeNi/NC@G). The P-FeNi/NC@G electrode exhibits a superior OER activity with an overpotential of 310 mV at 10 mA cm^-2 and an ORR performance with a half-wave potential of 0.81 V. With P-FeNi/NC@G as the air cathode, the integrated all-solid-state rechargeable zinc-air battery presents a high open-circuit voltage of 1.53 V, a high peak power density of 159 mW cm^-2, a small charge-discharge voltage gap of 0.73 V at 5 mA cm^-2, as well as excellent long-term stability up to 144 cycles. This work not only expands the air cathode materials database but also develops a new co-doped synthesis method that can be utilized to fabricate a cathode with promoted catalytic efficiency, resulting in improved performance for an all-solid-state zinc-air battery.