Nanofiltration contributes to the development of advanced treatment of wastewater. An antifouling mixed matrix recycled polyethylene terephthalate (rPET) membrane modified by the hydrophilic ZnO/y-FeOOH nanoparticles (NPs) was fabricated via the electrospinning method. The effect of ZnO/y-FeOOH NPS embedded in rPET as a modifier on the fabrication of nanocomposite membranes was investigated regarding water flux, membrane morphology, permeability, fouling resistance, and COD removal. The surface morphology of the rPET-ZnO/y-FeOOH membrane was evaluated by field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), water contact angle (WCA), and porosity and pore structure.Due to the embedding of NPs, the resulting rPET-ZnO/y-FeOOH membrane, with a low WCA of 53.404° angle, conforms significantly improved hydrophilicity and water permeation flux. The FESEM image displayed the distribution of cuboidal and needle-like ZnO and FeOOH NPs on the rPET membrane. The performance of the nanofiltration system related to the removal efficiency of COD was studied. It was deduced that the rPET-ZnO/y-FeOOH membrane had a superior COD removal capability (95.7%) at a pressure of 2 bar. Protein rejection tests were performed on antifouling behavior. The nanocomposite membrane with a high antifouling capability was related to 0.5 wt·% ZnO/y-FeOOH NPs (flux recovery ratio [FRR] = 96.2%, Rr = 90.21%, and Rir = 3.001%). The modification procedure in this study (as a great improving technique) was proposed to fabricate the antifouling nanofiltration membrane.
Keywords: Antifouling; COD removal; Nanofiltration; Water reuse; ZnO/y-FeOOH; rPET membrane.
© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.