The improved performance and mechanism of solution-processed blue PhOLEDs based on double electron transport layers

Zijian Liu; WeiYe Zheng; Peng Wei; Zheng Xu; Dandan Song; Bo Qiao; Suling Zhao

doi:10.1039/d0ra00515k

The improved performance and mechanism of solution-processed blue PhOLEDs based on double electron transport layers

RSC Adv. 2020 Apr 1;10(22):13215-13222. doi: 10.1039/d0ra00515k. eCollection 2020 Mar 30.

Authors

Zijian Liu^{1

2}, WeiYe Zheng^{1

2}, Peng Wei^{1

2}, Zheng Xu^{1

2}, Dandan Song^{1

2}, Bo Qiao^{1

2}, Suling Zhao^{1

2}

Affiliations

¹ Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education Beijing 100044 China.
² Institute of Optoelectronics Technology, Beijing Jiaotong University Beijing 100044 China.

Abstract

Performance improved solution-processed blue phosphorescent organic light emitting diodes (PhOLEDs) are demonstrated by adopting a double electron transport layer (ETL) strategy, which consists of TPBi and an additional Alq₃ ETL. With the help of Alq₃ ETL, the performance of the optimal device with a double ETL is significantly enhanced. The maximum luminance of OLEDs is improved from 6787 cd m^-2 to 13 054 cd m^-2, and the maximum current efficiency is increased from 3.9 cd A^-1 to 11.4 cd A^-1. Furthermore, the difference of carrier injection in the two types of PhOLEDs is explored by using the transient electroluminescence measurement method. The results imply that double ETL can help to balance electron injection and carrier transport, reduce the interface charge accumulation, leading to a high efficiency. The PL decay of the emission layer with different ETL is detected to analyze the effect of the introduced second ETL layer and the interface on the exciton decay of the emission layer. The results show that the introduced interface in devices with a double ETL has an adverse effect on the exciton emission, which contributes to the serious efficiency roll-off of devices with a double ETL.