The slow redox kinetics of polysulfide hinders the rapid and complete conversion between soluble polysulfides and Li2S2/Li2S, resulting in unsatisfactory rate and cycle performance in lithium-sulfur batteries. Electrochemical catalysis, one effective method, promotes the reaction kinetics and inhibits the "shuttle effect". Here, we present a three-dimensional ordered macro-porous carbon with abundant cobalt-nitrogen-carbon active sites as a matrix catalyst, leading to accelerated polysulfide redox kinetics. In addition, the interconnected conductive frameworks with ordered macro-porous carbon afford fast ion/electron transport and provide sufficient space to adapt to the volume expansion of the sulfur electrode. Owing to the aforementioned advantages, a lithium-sulfur battery with the matrix catalyst delivers a high specific capacity (1140 mA h g-1 at 0.1C) and a low capacity decay rate (0.0937% per cycle over 500 cycles). Moreover, there is a high rate capacity (349.1 mA h g-1) even at the high current density of 2C and sulfur loading of 3.8 mg cm-2 due to the improved polysulfide redox kinetics by a catalytic effect.
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