The relationships between Momentary Psychotic-Like Experiences (MPLEs) and HEXACO-complemented by the proneness to PLEs conceptualized as a basic personality trait (Disintegration), and a maladaptive trait (PID-5 Psychoticism)-were investigated in a prospective study that includes experience-sampling methodology (ESM). The main goal was to investigate whether MPLEs are better predicted by HEXACO or measures of the dispositional proneness to PLEs. A sample of 180 participants assessed MPLEs and affective states they experienced in the previous two hours, twice per day, with semi-randomly set assessment time-points, during seven days, by using ESM. Personality inventories were administered 1-2 months earlier. MPLEs were better predicted by the measures of dispositional tendencies toward PLEs than by the HEXACO, no matter whether it was broadly defined as the nine-faceted general tendency toward PLEs (Disintegration), or narrowly as three-faceted positive psychotic-like symptoms of maladaptive personality tendencies (PID-5-Psychoticism).