Two-step facile synthesis of Co3O4@C reinforced PbO2 coated electrode to promote efficient oxygen evolution reaction for zinc electrowinning

Wenhao Jiang; Junli Wang; Xuanbing Wang; Jiang Liao; Jinlong Wei; Ruidong Xu; Linjing Yang

doi:10.1039/d1ra09100j

Two-step facile synthesis of Co₃O₄@C reinforced PbO₂ coated electrode to promote efficient oxygen evolution reaction for zinc electrowinning

RSC Adv. 2022 Apr 6;12(17):10634-10645. doi: 10.1039/d1ra09100j. eCollection 2022 Mar 31.

Authors

Wenhao Jiang^{1

2}, Junli Wang³, Xuanbing Wang^{1

2}, Jiang Liao¹, Jinlong Wei², Ruidong Xu^{1

2}, Linjing Yang^{1

2}

Affiliations

¹ State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology Kunming 650093 China eslinjingyang@kust.edu.cn rdxupaper@aliyun.com.
² Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology Kunming 650093 China.
³ Researcher Center for Analysis and Measurement, Kunming University of Science and Technology Kunming 650093 China.

Abstract

The conventional Pb-Ag alloy possesses a high oxygen evolution reaction overpotential, poor stability, and short service life in acidic solutions, making it an unsuitable sort of anode material for the zinc electrowinning process. Therefore, a layered carbon-covered cobalt tetroxide (Co₃O₄@C)-reinforced PbO₂-coated electrode is fabricated via a facile two-step pyrolysis-oxidation and subsequent electrodeposition process. As a result, the reinforced PbO₂-coated electrode exhibits a low OER overpotential of 517 mV at 500 A m^-2 and a Tafel slope of 0.152 V per decade in a zinc electrowinning simulation solution (0.3 M ZnSO₄ and 1.53 M H₂SO₄). The reduced overpotential of 431 mV at 500 A m^-2 compared to traditional Pb-0.76%Ag alloy leads to improved energy savings, which is attributable to the presence of Co₃O₄@C to refine the grain size and thus increase the effective contact area. Moreover, the reinforced PbO₂-coated electrode has a prolonged service life of 93 h at 20 000 A m^-2 in 1.53 M H₂SO₄. Therefore, an accessible and efficient strategy for preparing a coated electrode to improve OER performance for zinc electrowinning is presented in this research.