Because of the advantages of a uniform distribution of reinforcing particles and in situ preparation, in situ precipitation has become an important way to prepare magnetic and other smart hydrogels. An important step in this process is to immerse hydrogels in alkaline solution to implant magnetic particles. Previous studies generally have ignored the effect of this process on the network structure and mechanical properties of hydrogels. In this study, we immersed polyvinyl alcohol (PVA) hydrogel samples in sodium hydroxide solutions of different concentrations to study changes in mechanical properties, such as stress-strain relationship, self-recovery, and fracture failure. The results showed that after the immersion process, the hydrogel's tensile and compressive properties changed significantly, and the failure behavior changed from brittle fracture to ductile fracture. Through a microscopic mechanism, the alkaline solution caused a high degree of phase separation and crystallization within the polymer network, thereby changing the PVA hydrogel network from a single phase to a multiphase. Hence, we used a continuous multiphase network model with a certain probability distribution to describe this tensile behavior. This model well described the stress-strain relationship of the hydrogel from stretching to fracture and revealed that the macroscopic failure corresponded to the peak of fracture distribution. Studies have shown that attention should be paid to the influence of the in situ precipitation on the mechanical properties, and the probabilistic multiphase network model can be used to predict the mechanical behavior of hydrogels with multiple phase separation.
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