Binary self-assembly of ordered Bi4Se3/Bi2O2Se lamellar architecture embedded into CNTs@Graphene as a binder-free electrode for superb Na-Ion storage

Honglang Liu; Dan Li; Hanhao Liu; Chao Wang; Yanzhong Wang; Yanjun Chen; Yaoyao Linghu; Zhen Tian; Huaihe Song; Jisheng Zhou; Li Guo

doi:10.1016/j.jcis.2022.03.129

Binary self-assembly of ordered Bi₄Se₃/Bi₂O₂Se lamellar architecture embedded into CNTs@Graphene as a binder-free electrode for superb Na-Ion storage

J Colloid Interface Sci. 2022 Aug 15:620:168-178. doi: 10.1016/j.jcis.2022.03.129. Epub 2022 Mar 31.

Authors

Honglang Liu¹, Dan Li², Hanhao Liu¹, Chao Wang¹, Yanzhong Wang¹, Yanjun Chen¹, Yaoyao Linghu¹, Zhen Tian¹, Huaihe Song³, Jisheng Zhou³, Li Guo⁴

Affiliations

¹ School of Materials Science and Engineering, North University of China, Taiyuan, China; Advanced Energy Materials and Systems Institute, North University of China, Taiyuan, China.
² School of Materials Science and Engineering, North University of China, Taiyuan, China; Advanced Energy Materials and Systems Institute, North University of China, Taiyuan, China. Electronic address: lidanbuct@163.com.
³ State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, PR China.
⁴ Advanced Energy Materials and Systems Institute, North University of China, Taiyuan, China. Electronic address: guoli@nuc.edu.cn.

PMID: 35421753
DOI: 10.1016/j.jcis.2022.03.129

Abstract

With the development of various flexible electronic devices, flexible energy storage devices have attracted more research attention. Binder-free flexible batteries, without a current collector, binder, and conductive agent, have higher energy density and lower manufacturing costs than traditional sodium-ion batteries (SIBs). However, preparing binder-free anodes with high electrochemical performance and flexibility remains a great challenge. In this study, a binary self-assembly composite of an ordered Bi₄Se₃/Bi₂O₂Se lamellar architecture wrapped by carbon nanotubes (CNTs) was embedded in graphene with strong interfacial interaction to form Bi₂O₂Se/Bi₄Se₃@CNTs@rGO (BCG), which was used as a binder-free anode for SIBs. A unique "one-changes-into-two" phenomenon was observed: the layered Bi₂Se₃ was transformed into a unique layered Bi₄Se₃/Bi₂O₂Se heterojunction structure, which not only provides more electrochemical channels but also reduces internal stress to improve the stability of the material structure. BCG-2 showed excellent sodium-ion storage, delivering a reversible capacity of 346 mA h/g at 100 mA/g and maintaining a capacity of 235 mA h/g over 50 cycles. Even at a high current density of 1 A/g, it retains a capacity of 105 mA h/g after 1000 cycles. This unique design concept can also be employed in synthesizing other binder-free electrodes to improve their properties.

Keywords: Binder-free electrodes; Bismuth selenide; Heterojunction; Interfacial interaction; Sodium-ion battery.