Edge-enriched MoS2 nanosheets modified porous nanosheet-assembled hierarchical In2O3 microflowers for room temperature detection of NO2 with ultrahigh sensitivity and selectivity

Abstract

Nitrogen dioxide (NO₂) is one of the most hazardous toxic pollutants to human health and the environment. However, deficiencies of low sensitivity and poor selectivity at room temperature (RT) restrain the application of NO₂ sensors. Herein, the edge-enriched MoS₂ nanosheets modified porous nanosheets-assembled three-dimensional (3D) In₂O₃ microflowers have been synthesized to improve the sensitivity and selectivity of NO₂ detection at RT. The results show that the In₂O₃/MoS₂ composite sensor exhibits a response as high as 343.09-5 ppm NO₂, which is 309 and 72.5 times higher than the sensors based on the pristine MoS₂ and In₂O₃. The composite sensor also shows short recovery time (37 s), excellent repeatability and long-term stability. Furthermore, the response of the In₂O₃/MoS₂ sensor to NO₂ is at least 30 times higher than that of other gases, proving the ultrahigh selectivity of the sensor. The outstanding sensing performance of the In₂O₃/MoS₂ sensor can be attributed to the synergistic effect and abundant active sites originating from the p-n heterojunction, exposed edge structures and the designed 2D/3D hybrid structure. The strategy proposed herein is expected to provide a useful reference for the development of high-performance RT NO₂ sensors.

Keywords: Edge activity; Heterojunction; High selectivity; In(2)O(3)/MoS(2); NO(2) sensor.