Regioisomeric core-shell cuprofullerene C60@Cu24

You-Shi Guo; Shun-Ze Zhan; Jia-Jing Zhong; Weigang Lu; Seik Weng Ng; Dan Li

doi:10.1039/d2cc00683a

Regioisomeric core-shell cuprofullerene C₆₀@Cu₂₄

Chem Commun (Camb). 2022 May 3;58(36):5470-5473. doi: 10.1039/d2cc00683a.

Authors

You-Shi Guo¹, Shun-Ze Zhan^{1

2}, Jia-Jing Zhong¹, Weigang Lu², Seik Weng Ng³, Dan Li²

Affiliations

¹ Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou 515063, P. R. China. szzhan@stu.edu.cn.
² College of Chemistry and Materials Science, and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, P. R. China. danli@jnu.edu.cn.
³ UCSI University, Cheras, Kuala Lumpur, Malaysia.

PMID: 35416208
DOI: 10.1039/d2cc00683a

Abstract

The controlled synthesis of high-nuclear regioisomeric core-shell exohedral metallofullerenes (ExMFs) is challenging. Herein, we demonstrated the synthesis of regioisomeric core-shell cuprofullerene C₆₀@Cu^I₂₄ and its 3-D coordination polymer using heteroleptic ligands, realizing high-nuclear regioisomeric ExMFs and a polymeric ExMF structure.