Nanofluid preparation, stability and performance for CO2 absorption and desorption enhancement: A review

Abstract

In recent years, the importance of capturing CO₂ has increased due to the necessity of minimizing climate change and the detrimental effects of CO₂ emissions from industrial processes. CO₂ absorption, as one of the most mature carbon capture technologies, has been improved by introducing nanosized particles into liquid absorbents. Nanofluids have been the subject of interest in many studies recently due to their tremendous impact on absorption. This review comprehensively examines the CO₂ absorption behavior for nanofluids through the investigation of different absorption systems. Potential mechanisms for improving the absorption/regeneration performance of nanoabsorbents as well as the synergistic effects of physicochemical properties of nanofluids, such as viscosity and density on CO₂ capture behavior, are reviewed. Nanofluid enhancement factors in terms of absorption rate and capacity towards CO₂ are also compiled. Mathematical models, which have been proposed for calculating mass transfer coefficient and mass diffusivity, are comprehensively outlined. The paper discusses conventional methods for nanofluid preparation affecting the physicochemical properties of nanofluids. Strategies for enhancing nanofluid stability, as well as approaches to examine their stability are discussed. Finally, nanoparticle concentration, types and size of them, and selection of the base liquid absorbent as the key factors influencing the CO₂ removal process by nanofluids, are considered in this paper, as well.

Keywords: Absorption; CO(2) capture; Mass-transfer; Nanofluid; Nanoparticle; Suspension stability.