In this work, we demonstrate an experimental realization of a granular multiferroic composite, where the magnetic state of a nanocrystal array is modified by tuning the interparticle exchange coupling using an applied electric field. Previous theoretical models of a granular multiferroic composite predicted a unique magnetoelectric coupling mechanism, in which the magnetic spins of the ensemble are governed by interparticle exchange. The extent of these exchange interactions can be controlled by varying the local dielectric environment between grains. We specifically utilize the strong dielectric dependence of ferroelectric materials to modify the interparticle coupling of closely spaced magnetic nanoparticles using either a change in temperature or an electric field. This coupling modifies the ensemble magnetic coercivity and thus the superparamagnetic-to-ferromagnetic phase transition temperature. Through the use of two different ferroelectrics, our results suggest that this magnetoelectric coupling mechanism could be generalized as a new class of multiferroic material, applicable to a broad range of ferroelectric/magnetic nanocrystal composites.
Keywords: exchange coupling; granular magnets; magnetic nanocrystals; magneto-electric materials; multiferroics.