Electrodialysis using anion-exchange membranes (AEMs) and cation-exchange membranes (CEMs) has been widely used for water desalination and the management of various ionic species. During commercial electrodialysis, the available area of an ion-exchange membrane is reduced by a non-conductive spacer that is in contact with the AEM/CEM. Although multiple reports have described the advantages or disadvantages of spacers, fewer studies have explored the effects of spacers on the mass transport effect of the reduced membrane area excluding the fluid flow change. In this paper, we present our experimental studies concerning mass transport in microfluidic electrodialysis systems with partially masked ion-exchange membranes. Six different types of masking membranes were prepared by the deposition of non-conductive films on parts of the membranes. The experimental results showed that the overlapped types (in which masking was vertically aligned in the AEM/CEM) exhibited a larger electrical conductance and better current/energy efficiency, compared with the non-overlapped types (in which masking was vertically dislocated in the AEM/CEM). We also observed that a reduction in the unit length of the unmasked ion-exchange membrane enhanced overall mass transport. Our results demonstrate the effects of patterned membranes on electrical resistance and desalination performance; they also identify appropriate arrangements for electromembrane systems.
Keywords: desalination; electroconvection; electrodialysis; ion exchange membrane; nanofluidics.