Polyethylene separator supported thin-film composite forward osmosis membranes for concentrating lithium enriched brine

Nan Sun; Pengjia Dou; Wentao Zhai; Hailong He; Long D Nghiem; Vahid Vatanpour; Yuebiao Zhang; Changkun Liu; Tao He

doi:10.1016/j.watres.2022.118297

Polyethylene separator supported thin-film composite forward osmosis membranes for concentrating lithium enriched brine

Water Res. 2022 Jun 1:216:118297. doi: 10.1016/j.watres.2022.118297. Epub 2022 Mar 14.

Authors

Nan Sun¹, Pengjia Dou², Wentao Zhai³, Hailong He⁴, Long D Nghiem⁵, Vahid Vatanpour⁶, Yuebiao Zhang⁴, Changkun Liu⁷, Tao He⁸

Affiliations

¹ Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China; School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China.
² College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China. Electronic address: doupj@szu.edu.cn.
³ Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China.
⁴ School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China.
⁵ Centre for Technology in Water and Wastewater, School of Civil and Environmental Engineering, University of Technology Sydney, NSW 2220, Australia.
⁶ Department of Applied Chemistry, Faculty of Chemistry, Kharazmi University, Tehran 15719-14911, Iran.
⁷ College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China.
⁸ Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China. Electronic address: het@sari.ac.cn.

PMID: 35325825
DOI: 10.1016/j.watres.2022.118297

Abstract

To extract lithium from salt lake brine involves a process of separation and concentration. After separating lithium from brine, the lithium ion concentration is generally a few hundred mg/L which is far below the required 20-30 g/L (as Li⁺) before precipitation as lithium carbonate. The concentration step of a lithium enriched brine is crucial but highly energy-intensive. Spontaneous forward osmosis (FO) technology offers the possibility for concentrating lithium ions with low energy. Because the concentrating process involves both feed and draw solution with very high salinity, it is highly desirable to have a high performance FO membrane with a low structural parameter as well as a high rejection to ions. In this work, thin polyethylene separator supported FO (PE-FO) membranes were prepared and post-treated stepwise with benzyl alcohol (BA) and hydraulic compaction. The effect of the post-treatment on the FO performance was systematically analyzed. Excellent FO performance was achieved: the water flux and reverse salt flux selectivity were 66.3 LMH and 5.25 L/g, respectively, when the active layer is oriented towards the 0.5 M NaCl draw solution with deionized water as the feed. To the best of our knowledge, this FO flux is the highest ever reported in the open literature under similar test conditions. Applied in concentrating lithium enriched brine, the membrane showed superior water flux using saturated MgCl₂ as draw solution. A new FO model was established to simulate the water flux during the concentration process with good agreement with the experimental results. The promising results using PE-FO membrane for lithium enrichment opens a new frontier for the potential application of FO membranes.

Keywords: Forward osmosis; Lithium; Membrane; Polyethylene; Post-treatment.