Great progress has been made in the development of various organic persistent luminescent (OPL) materials in the past few years, and increasing attention has been paid to their interesting applications in environmental sensing due to their long emission lifetimes and high sensitivity. Especially, the introduction of different halogen elements facilitates highly efficient OPL emission with distinct lifetimes and colours. In this review, we summarize the current status of the halide-containing OPL materials for environmental sensing applications. To begin with, the photophysical processes and luminescence mechanisms of OPL materials are expounded in detail to better understand the relationship among molecular structures, OPL properties, and sensing applications. Then, representative halide-containing material systems, such as small molecules, polymers, and doping systems, are summarized with their interesting applications in sensing temperature, oxygen, H2O, UV light and organic solvents. In addition, several challenges and future research opportunities in this field are discussed. This review aims to provide some reasonable guidance on the material design of OPL sensors and their practical applications, and tries to provide a new perspective on the application direction of organic optoelectronics.
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