Atmospheric transport drives regional interactions of ozone pollution in China

Abstract

In recent years, ozone pollution becomes a serious environmental issue in China. A good understanding of source-receptor relationships of ozone transport from aboard and inside China is beneficial to mitigating ozone pollution there. To date, these issues have not been comprehensively assessed, especially for highly polluted regions in the central and eastern China (CEC), including the North China Plain (NCP), Twain-Hu region (THR), Yangtze River Delta (YRD), Pearl River Delta (PRD), and Sichuan Basin (SCB). Here, based on simulations over 2013-2020 from a well-validated chemical transport model, GEOS-Chem, we show that foreign ozone accounts for a large portion of surface ozone over CEC, ranging from 25.0% in THR to 39.4% in NCP. Focusing on transport of domestic ozone between the five regions in CEC, we find that atmospheric transport can largely modulate regional interactions of ozone pollution in China. At the surface, THR receives the largest amount of ozone from the other four regions (54.2% of domestic ozone in the receptor region, the same in below), followed by PRD (32.3%), SCB (26.7%), YRD (21.1%), and NCP (18.0%). Meanwhile, YRD exports largest amount of ozone to the other regions, ranging from 8.9% in SCB to 28.4% in THR. Although SCB is relatively isolated and thus impacts NCP, YRD, and PRD weakly (< 2.2%), export of SCB ozone to THR reaches 9.3%. The regional ozone transport over CEC, occurring mostly in the lower troposphere, is mainly modulated by the East Asian monsoon circulations, proximity between source and receptor regions, seasonal changes of ozone production, and topography.

Keywords: China; Source-receptor relationship; Transport mechanism; Tropospheric ozone.