Degradation of bisphenol A: a contaminant of emerging concern, using catalytic ozonation by activated carbon impregnated nanocomposite-bimetallic catalyst

Abstract

Rampant water pollution events and rising water demand caused by exponential population growth and depleting freshwater resources speak of an impending water crisis. The inability of conventional wastewater treatment systems to remove contaminants of emerging concern (CECs) such as bisphenol A (BPA) beckons for new and efficient technologies to remove them from wastewater and water sources. Advanced oxidation processes such as ozonation are primarily known for their capability to oxidize and degrade organic entities in water, but optimum mineralization levels were hard to achieve. In this study, we synthesized an activated carbon impregnated nanocomposite-bimetallic catalyst (AC/CeO₂/ZnO) and used it along with ozonation to remove BPA from water. The catalyst was characterized using BET, XRD, FESEM, Raman spectra, and DLS studies. Catalytic ozonation achieved TOC removal 25% higher than non-catalytic ozonation process. The degradation pathway of BPA was proposed using LC-MS/LC-Q-TOF studies that found six main aromatic degradation byproducts. Catalytic ozonation and non-catalytic ozonation followed similar degradation pathways. The formation of persistent aliphatic acidic byproducts in the treated sample made total organic carbon (TOC) removal above 61% difficult.

Keywords: Bimetallic catalyst; Bisphenol A; Characterization; Contaminants; Degradation; Ozonation; Total organic carbon.