Glass is important as a substrate for coatings in a wide range of applications or as a substrate for the fabrication of optical micro/nano structures. Coating by wet chemistry methods often demands modifications of the glass surface properties involving several steps. In addition, the micro/nano structuring is usually a several-step process. New methods that are simpler and more efficient are being proposed. One of them is glass poling that has been used to obtain surface relief on glass and, together with electric field assisted dissolution, for metal nanostructures in glass/metal systems. In this work, we demonstrate that poling increases the susceptibility of the glass surface for coating with Ag nanoparticles synthesized in situ by silver salt reduction. It is shown that a selectively poled glass surface can be used as a template to obtain optical microstructures consisting of Ag nanoparticles in only three simple steps. As a proof-of-concept, the method is used to fabricate diffraction gratings with an optical response that can be tuned by adjusting the Ag concentration. This approach is more versatile than the standard structuring by electric field assisted dissolution, as it does not require application of an elevated temperature once the coating is formed, which might change or destroy the properties of the thermally sensitive coating species or morphologies.