Remediation and resource utilization of chromium(III)-containing tannery effluent based on chitosan-sodium alginate hydrogel

Xiaoyu Guan; Bingyuan Zhang; Dongping Li; Mengyan He; Qinxin Han; Jinming Chang

doi:10.1016/j.carbpol.2022.119179

Remediation and resource utilization of chromium(III)-containing tannery effluent based on chitosan-sodium alginate hydrogel

Carbohydr Polym. 2022 May 15:284:119179. doi: 10.1016/j.carbpol.2022.119179. Epub 2022 Jan 26.

Authors

Xiaoyu Guan¹, Bingyuan Zhang², Dongping Li², Mengyan He², Qinxin Han², Jinming Chang³

Affiliations

¹ College of Bioresources Chemical and Materials Engineering, National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science & Technology, Xi'an, Shaanxi 710021, PR China. Electronic address: guanxiaoyu@sust.edu.cn.
² College of Bioresources Chemical and Materials Engineering, National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science & Technology, Xi'an, Shaanxi 710021, PR China.
³ Institute of Applied Chemistry, China West Normal University, Nanchong 637009, PR China.

PMID: 35287899
DOI: 10.1016/j.carbpol.2022.119179

Abstract

In this work, chitosan‑sodium alginate polysaccharide hydrogel (CS_0.2-SA_0.6(GA_0.3)) was rationally designed and synthesized via electrostatic and covalent interactions. The structure and morphologies of the hydrogel were characterized, and the results showed CS_0.2-SA_0.6(GA_0.3) with a layered and loose structure by virtue of glutaraldehyde (GA) cross-linking agent introduction. On the one hand, the porous and loose structure of the adsorbent facilitated the removal of chromium (III) from the tannery effluent. Furthermore, after chromium (III) adsorption, CS_0.2-SA_0.6(GA_0.3)-Cr(III) could be mechanically degraded to CS/SA/GA/Cr(III) sol by a drum, avoiding traditional high-temperature, high-pressure reactor application. Due to the retanning and filling effects of CS/SA/GA/Cr(III) sol, the chemical and physical properties of the finished leather were improved. Based on these, this work aims to provide a strategy that integrates chromium (III)-containing tanning effluent treatment and retanning/filling resource utilization of adsorbent/adsorbate, which is an effective alternative on account of its convenient operation, environmental sustainability, and wide adaptability.

Keywords: Chitosan; Chromium (III)-contaminated effluent; Hydrogel; Remediation; Resource utilization; Sodium alginate.