Single Atom Catalysts: An Overview of the Coordination and Interactions with Metallic Supports

Abstract

Catalyst utilization is a key economic factor in heterogeneous catalysis, particularly, when noble metals are used as the active phase. A huge saving on catalyst cost can be achieved with developing a single atomic layer of the active catalyst on a given cheap support. Besides the economic benefit, single atom catalysts (SACs) have also shown superior activity and selectivity relative to catalytic particles or nanoparticles; yet they are prone to aggregation and deactivation. The development of effective, stable, and commercially viable SACs is still a huge challenge. One of the remaining key obstacles is the ability to easily and effectively tune SACs-support interactions and coordination in a way that enables the production of robust, stable, and versatile SACs. Accordingly, the coordination and interactions between metallic supports and SACs and their impacts on SACs stability and activity are reviewed in this article.

Keywords: Catalyst-support interactions; Coordination modes; Heterogeneous catalysis; Single atom catalysts (SACs); Supported catalysts.